article Open AccessTop 10% cited
Chiral and Achiral Crystal Structures
Helvetica Chimica Acta · 2003 · Vol. 86(4) · pp. 905–921
H. D. Flack✉(University of Geneva)
Abstract
Abstract An extensive study and analysis of the concepts, classification, presentation, and nomenclature of chirality and lack of chirality in crystal structures and their constituents is presented. Oriented crystal structures are classified. The chirality rules for existence of molecular crystal structures are examined and the relation to segmentation and latent symmetry highlighted. The nomenclature of chirality and related terms, and the relationship of chirality to optical activity is covered. The uses and limitations of the Euclidean normalizer are treated. An improved glossary of terms is included.
Molecular spectroscopy and chiralityCrystallography and molecular interactionsCrystallization and Solubility StudiesChirality (physics)ChemistryNomenclatureCrystal structurePlanar chiralityAxial chiralityCrystallographyStereochemistryEnantioselective synthesisPhysics
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References
Basic terminology of stereochemistry (IUPAC Recommendations 1996)
Pure and Applied Chemistry · 1996 · 860 citations
Reporting and evaluating absolute-structure and absolute-configuration determinations
Journal of Applied Crystallography · 2000 · 1,004 citations
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