articleTop 10% cited
Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks
Dalton Transactions · 2012 · Vol. 41(18) · pp. 5458–5458
Adam F. Gross✉(HRL Laboratories (United States))Elena Sherman(HRL Laboratories (United States))John J. Vajo(HRL Laboratories (United States))
Abstract
Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent.
Metal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and CharacterizationCovalent Organic Framework ApplicationsSodaliteZeolitic imidazolate frameworkAqueous solutionCobaltImidazolateLigand (biochemistry)Metal-organic frameworkChemistryZincDeprotonation
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References
Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks
Accounts of Chemical Research · 2009 · 2,570 citations
Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0
Tetrahedron · 2008 · 1,061 citations
Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework
Chemistry of Materials · 2009 · 1,308 citations
Rapid synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals in an aqueous system
Chemical Communications · 2011 · 1,673 citations
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Proceedings of the National Academy of Sciences · 2006 · 7,256 citations
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