articleTop 1% cited
Fast Lithium Ion Conduction in Garnet‐Type Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub>
Angewandte Chemie International Edition · 2007 · Vol. 46(41) · pp. 7778–7781
Ramaswamy Murugan✉(Kiel University)Venkataraman Thangadurai(University of Calgary)W. Weppner(Kiel University)
Abstract
Low activation energy and fast lithium ion conduction have been observed for the new compound Li7La3Zr2O12. Relative to previously reported lithium garnets, the solid electrolyte shows a larger cubic lattice constant, higher lithium ion concentration, lower degree of chemical interaction between the Li+ ions and the other lattice constituents, and higher densification.
Advanced Battery Materials and TechnologiesCrystal Structures and PropertiesSolid-state spectroscopy and crystallographyIonLithium (medication)Fast ion conductorElectrolyteLattice constantLattice (music)Thermal conductionMaterials scienceActivation energyAnalytical Chemistry (journal)
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Solid State Communications · 1993 · 1,553 citations
Electroceramics: Characterization by Impedance Spectroscopy
Advanced Materials · 1990 · 2,656 citations
Novel Fast Lithium Ion Conduction in Garnet‐Type Li <sub>5</sub> La <sub>3</sub> M <sub>2</sub> O <sub>12</sub> (M = Nb, Ta)
Journal of the American Ceramic Society · 2003 · 766 citations
Crystal structure and ionic conductivity of Li14Zn(GeO4)4 and other new Li+ superionic conductors
Materials Research Bulletin · 1978 · 535 citations
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