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Structure of tris(2,2′-bipyridyl)ruthenium(<scp>II</scp>) hexafluorophosphate, [Ru(bipy)<sub>3</sub>][PF<sub>6</sub>]<sub>2</sub>; X-ray crystallographic determination

Abstract

Analysis of Ru–N bond lengths based on an X-ray crystallographic determination of the molecular structure of [Ru(bipy)3]2+ and on reactivity patterns of various [Ru(bipy)3]n+ species suggests that members of the series have similar structures; this similarity may be important in the development of new solar energy catalysts.

Metal complexes synthesis and propertiesOrganometallic Complex Synthesis and CatalysisMagnetism in coordination complexesRutheniumHexafluorophosphateTrisCrystallographyChemistryX-ray crystallographyMoleculeReactivity (psychology)Crystal structureCatalysis
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