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Simplification of the molecular vibration-rotation hamiltonian
Molecular Physics · 1968 · Vol. 15(5) · pp. 479–490
Abstract
By use of the commutation relations and sum rules, the Darling-Dennison vibration-rotation hamiltonian for a non-linear molecule is rearranged to the form: The order of the factors in the first term is immaterial, on account of the relation: A simple expansion is given for the μαβ tensor in terms of the normal coordinates.
Molecular spectroscopy and chiralityElectron Spin Resonance StudiesHamiltonian (control theory)VibrationCommutationClassical mechanicsPhysicsTensor (intrinsic definition)Normal coordinatesMathematicsQuantum mechanicsMolecule
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