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A facile synthesis of UiO-66, UiO-67 and their derivatives

Chemical Communications · 2013 · Vol. 49(82) · pp. 9449–9449
Michael J. KatzZachary J. BrownYamil J. ColónPaul W. SiuKarl A. ScheidtRandall Q. SnurrJoseph T. HuppOmar K. Farha

Abstract

A scalable, reproducible method of synthesizing UiO-66- and UiO-67-type MOFs, entailing the addition of HCl to the reaction mixture, has been investigated. The new protocol requires a fraction of the time of previously reported procedures, yields exceptional porosities, and works with a range of linkers.

Metal-Organic Frameworks: Synthesis and ApplicationsLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and ApplicationsCombinatorial chemistryReaction conditionsScalabilityFraction (chemistry)ChemistryNanotechnologyMaterials scienceComputer scienceCatalysisOrganic chemistry
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